Abstract
A rhodium-catalyzed method for the synthesis of organophosphorus compounds directly from organosulfur compounds was developed. In the presence of RhH(PPh3)4 and depe, the reaction of 1-alkylthioalkynes with tetraethyldiphosphine disulfide gave 1-alkynylphosphine sulfides. The same complex catalyzed the reaction of thioesters giving acylphosphine sulfides.
Original language | English |
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Pages (from-to) | 2410-2412 |
Number of pages | 3 |
Journal | Tetrahedron Letters |
Volume | 52 |
Issue number | 18 |
DOIs | |
Publication status | Published - 2011 May 4 |
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry