Direct transformation of organosulfur compounds to organophosphorus compounds: Rhodium-catalyzed synthesis of 1-alkynylphosphine sulfides and acylphosphine sulfides

Mieko Arisawa; Takuya Watanabe; Masahiko Yamaguchi

doi:10.1016/j.tetlet.2011.02.112

Direct transformation of organosulfur compounds to organophosphorus compounds: Rhodium-catalyzed synthesis of 1-alkynylphosphine sulfides and acylphosphine sulfides

Mieko Arisawa, Takuya Watanabe, Masahiko Yamaguchi

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A rhodium-catalyzed method for the synthesis of organophosphorus compounds directly from organosulfur compounds was developed. In the presence of RhH(PPh₃)₄ and depe, the reaction of 1-alkylthioalkynes with tetraethyldiphosphine disulfide gave 1-alkynylphosphine sulfides. The same complex catalyzed the reaction of thioesters giving acylphosphine sulfides.

Original language	English
Pages (from-to)	2410-2412
Number of pages	3
Journal	Tetrahedron Letters
Volume	52
Issue number	18
DOIs	https://doi.org/10.1016/j.tetlet.2011.02.112
Publication status	Published - 2011 May 4

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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abstract = "A rhodium-catalyzed method for the synthesis of organophosphorus compounds directly from organosulfur compounds was developed. In the presence of RhH(PPh3)4 and depe, the reaction of 1-alkylthioalkynes with tetraethyldiphosphine disulfide gave 1-alkynylphosphine sulfides. The same complex catalyzed the reaction of thioesters giving acylphosphine sulfides.",

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AU - Watanabe, Takuya

AU - Yamaguchi, Masahiko

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AB - A rhodium-catalyzed method for the synthesis of organophosphorus compounds directly from organosulfur compounds was developed. In the presence of RhH(PPh3)4 and depe, the reaction of 1-alkylthioalkynes with tetraethyldiphosphine disulfide gave 1-alkynylphosphine sulfides. The same complex catalyzed the reaction of thioesters giving acylphosphine sulfides.

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