Direct observation of photochromic dynamics in the crystalline state of an organorhodium dithionite complex

Hidetaka Nakai; Motohiro Mizuno; Takanori Nishioka; Nobuaki Koga; Kimie Shiomi; Yousuke Miyano; Masahiro Irie; Brian K. Breedlove; Isamu Kinoshita; Yoshihito Hayashi; Yoshiki Ozawa; Takae Yonezawa; Koshiro Toriumi; Kiyoshi Isobe

doi:10.1002/anie.200601702

Direct observation of photochromic dynamics in the crystalline state of an organorhodium dithionite complex

Hidetaka Nakai, Motohiro Mizuno, Takanori Nishioka, Nobuaki Koga, Kimie Shiomi, Yousuke Miyano, Masahiro Irie, Brian K. Breedlove, Isamu Kinoshita, Yoshihito Hayashi, Yoshiki Ozawa, Takae Yonezawa, Koshiro Toriumi, Kiyoshi Isobe

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

(Chemical Equation Presented) Fully reversible crystal photochromism between the μ-O₂SSO₂ (1) and μ-O₂SOSO (2) forms of a dinuclear rhodium complex has been observed. The photochromic reaction, including stereoselective oxygen-atom transfer and stereospecific transformation of photochemically generated μ-O₂SOSO isomers into the most stable isomer, was directly followed by conventional single-crystal X-ray diffraction.

Original language	English
Pages (from-to)	6473-6476
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	39
DOIs	https://doi.org/10.1002/anie.200601702
Publication status	Published - 2006 Oct 6
Externally published	Yes

Keywords

Photochemistry
Photochromism
Rhodium
S ligands
Solid-state reactions

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200601702

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Nakai, H., Mizuno, M., Nishioka, T., Koga, N., Shiomi, K., Miyano, Y., Irie, M., Breedlove, B. K., Kinoshita, I., Hayashi, Y., Ozawa, Y., Yonezawa, T., Toriumi, K., & Isobe, K. (2006). Direct observation of photochromic dynamics in the crystalline state of an organorhodium dithionite complex. Angewandte Chemie - International Edition, 45(39), 6473-6476. https://doi.org/10.1002/anie.200601702

Nakai, H, Mizuno, M, Nishioka, T, Koga, N, Shiomi, K, Miyano, Y, Irie, M, Breedlove, BK, Kinoshita, I, Hayashi, Y, Ozawa, Y, Yonezawa, T, Toriumi, K & Isobe, K 2006, 'Direct observation of photochromic dynamics in the crystalline state of an organorhodium dithionite complex', Angewandte Chemie - International Edition, vol. 45, no. 39, pp. 6473-6476. https://doi.org/10.1002/anie.200601702

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abstract = "(Chemical Equation Presented) Fully reversible crystal photochromism between the μ-O2SSO2 (1) and μ-O2SOSO (2) forms of a dinuclear rhodium complex has been observed. The photochromic reaction, including stereoselective oxygen-atom transfer and stereospecific transformation of photochemically generated μ-O2SOSO isomers into the most stable isomer, was directly followed by conventional single-crystal X-ray diffraction.",

keywords = "Photochemistry, Photochromism, Rhodium, S ligands, Solid-state reactions",

author = "Hidetaka Nakai and Motohiro Mizuno and Takanori Nishioka and Nobuaki Koga and Kimie Shiomi and Yousuke Miyano and Masahiro Irie and Breedlove, {Brian K.} and Isamu Kinoshita and Yoshihito Hayashi and Yoshiki Ozawa and Takae Yonezawa and Koshiro Toriumi and Kiyoshi Isobe",

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doi = "10.1002/anie.200601702",

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AU - Nakai, Hidetaka

AU - Mizuno, Motohiro

AU - Nishioka, Takanori

AU - Koga, Nobuaki

AU - Shiomi, Kimie

AU - Miyano, Yousuke

AU - Irie, Masahiro

AU - Breedlove, Brian K.

AU - Kinoshita, Isamu

AU - Hayashi, Yoshihito

AU - Ozawa, Yoshiki

AU - Yonezawa, Takae

AU - Toriumi, Koshiro

AU - Isobe, Kiyoshi

PY - 2006/10/6

Y1 - 2006/10/6

N2 - (Chemical Equation Presented) Fully reversible crystal photochromism between the μ-O2SSO2 (1) and μ-O2SOSO (2) forms of a dinuclear rhodium complex has been observed. The photochromic reaction, including stereoselective oxygen-atom transfer and stereospecific transformation of photochemically generated μ-O2SOSO isomers into the most stable isomer, was directly followed by conventional single-crystal X-ray diffraction.

AB - (Chemical Equation Presented) Fully reversible crystal photochromism between the μ-O2SSO2 (1) and μ-O2SOSO (2) forms of a dinuclear rhodium complex has been observed. The photochromic reaction, including stereoselective oxygen-atom transfer and stereospecific transformation of photochemically generated μ-O2SOSO isomers into the most stable isomer, was directly followed by conventional single-crystal X-ray diffraction.

KW - Photochemistry

KW - Photochromism

KW - Rhodium

KW - S ligands

KW - Solid-state reactions

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Direct observation of photochromic dynamics in the crystalline state of an organorhodium dithionite complex

Abstract

Keywords

ASJC Scopus subject areas

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