TY - JOUR
T1 - Direct observation of correlation between electron emission and fragmentation into ions following B 1s excitation of the BF3 molecule
AU - Ueda, K.
AU - Ohmori, K.
AU - Okunishi, M.
AU - Chiba, H.
AU - Shimizu, Y.
AU - Sato, Y.
AU - Hayaishi, T.
AU - Shigemasa, E.
AU - Yagishita, A.
N1 - Copyright:
Copyright 2015 Elsevier B.V., All rights reserved.
PY - 1995
Y1 - 1995
N2 - An alternative technique of coincidence between energy-selected electrons and mass- and energy-selected photoions, combined with angle-resolved photoion spectroscopy, has been applied to investigate the state-selected dissociation dynamics of the B 1s core-excited BF3 molecule. Dissociation from the spectator Auger final states both above and below the double-ionization threshold produces energetic B+ in the secondary processes of stepwise dissociation after the molecular deformation (D3h→C3v), in marked contrast to dissociation following B 1s ionization in which energetic F+ is ejected within the D3h plane of the parent BF3 molecule.
AB - An alternative technique of coincidence between energy-selected electrons and mass- and energy-selected photoions, combined with angle-resolved photoion spectroscopy, has been applied to investigate the state-selected dissociation dynamics of the B 1s core-excited BF3 molecule. Dissociation from the spectator Auger final states both above and below the double-ionization threshold produces energetic B+ in the secondary processes of stepwise dissociation after the molecular deformation (D3h→C3v), in marked contrast to dissociation following B 1s ionization in which energetic F+ is ejected within the D3h plane of the parent BF3 molecule.
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U2 - 10.1103/PhysRevA.52.R1815
DO - 10.1103/PhysRevA.52.R1815
M3 - Article
AN - SCOPUS:0001482785
VL - 52
SP - R1815-R1818
JO - Physical Review A - Atomic, Molecular, and Optical Physics
JF - Physical Review A - Atomic, Molecular, and Optical Physics
SN - 1050-2947
IS - 3
ER -