Direct EPR observations of both oxidized and reduced porphyrin dimers in the lowest excited states: A novel analysis of a homobiradical with a strong antiferromagnetic interaction

Fumio Furuya, Kazuyuki Ishii, Nagao Kobayashi

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

The oxidized and reduced forms of bis(tetra-tert-butyltetraazaporphinato)lutetium (III) (Lu(TAP)2) have been examined by time-resolved EPR (TREPR) spectroscopy, showing both the first EPR investigation of a homobiradical with a strong antiferromagnetic interaction and usefulness of TREPR for investigating excited-state properties of different oxidation states.

Original languageEnglish
Pages (from-to)12652-12653
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number43
DOIs
Publication statusPublished - 2002 Oct 30

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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