TY - JOUR
T1 - Direct detection of the mercury-nitrogen bond in the thymine-HgII-thymine base-pair with 199Hg NMR spectroscopy
AU - Dairaku, Takenori
AU - Furuita, Kyoko
AU - Sato, Hajime
AU - Šebera, Jakub
AU - Yamanaka, Daichi
AU - Otaki, Hiroyuki
AU - Kikkawa, Shoko
AU - Kondo, Yoshinori
AU - Katahira, Ritsuko
AU - Matthias Bickelhaupt, F.
AU - Fonseca Guerra, Célia
AU - Ono, Akira
AU - Sychrovský, Vladimír
AU - Kojima, Chojiro
AU - Tanaka, Yoshiyuki
N1 - Publisher Copyright:
© The Royal Society of Chemistry.
PY - 2015/5/18
Y1 - 2015/5/18
N2 - We have observed the 1-bond 199Hg-15N J-coupling (1J(199Hg,15N) = 1050 Hz) within the HgII-mediated thymine-thymine base pair (T-HgII-T). This strikingly large 1J(199Hg,15N) is the first one for canonical sp2-nitrogen atoms, which can be a sensitive structure-probe of N-mercurated compounds and a direct evidence for N-mercuration. This journal is
AB - We have observed the 1-bond 199Hg-15N J-coupling (1J(199Hg,15N) = 1050 Hz) within the HgII-mediated thymine-thymine base pair (T-HgII-T). This strikingly large 1J(199Hg,15N) is the first one for canonical sp2-nitrogen atoms, which can be a sensitive structure-probe of N-mercurated compounds and a direct evidence for N-mercuration. This journal is
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U2 - 10.1039/c5cc02423d
DO - 10.1039/c5cc02423d
M3 - Article
C2 - 25891069
AN - SCOPUS:84928969195
VL - 51
SP - 8488
EP - 8491
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 40
ER -