Direct cyclic carbonate synthesis from CO2 and diol over carboxylation/hydration cascade catalyst of CeO2 with 2-cyanopyridine

Masayoshi Honda; Masazumi Tamura; Kenji Nakao; Kimihito Suzuki; Yoshinao Nakagawa; Keiichi Tomishige

doi:10.1021/cs500301d

Direct cyclic carbonate synthesis from CO₂ and diol over carboxylation/hydration cascade catalyst of CeO₂ with 2-cyanopyridine

Masayoshi Honda, Masazumi Tamura, Kenji Nakao, Kimihito Suzuki, Yoshinao Nakagawa, Keiichi Tomishige

ENG - Applied Chemistry

Research output: Contribution to journal › Review article › peer-review

113 Citations (Scopus)

Abstract

We first achieved direct synthesis of propylene carbonate from CO ₂ and 1,2-propanediol in excellent yield (>99%) using a carboxylation/hydration cascade catalyst of CeO₂ with 2-cyanopyridine. The catalyst system can be applied to syntheses of various cyclic carbonates, including 6-membered ring carbonates that are difficult to synthesize in high yields (62->99%).

Original language	English
Pages (from-to)	1893-1896
Number of pages	4
Journal	ACS Catalysis
Volume	4
Issue number	6
DOIs	https://doi.org/10.1021/cs500301d
Publication status	Published - 2014 Jun 6

Keywords

Cerium oxide
carbonate
carboxylation
hydration

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1021/cs500301d

Cite this

Direct cyclic carbonate synthesis from CO₂ and diol over carboxylation/hydration cascade catalyst of CeO₂ with 2-cyanopyridine. / Honda, Masayoshi; Tamura, Masazumi; Nakao, Kenji; Suzuki, Kimihito; Nakagawa, Yoshinao ; Tomishige, Keiichi.

In: ACS Catalysis, Vol. 4, No. 6, 06.06.2014, p. 1893-1896.

Research output: Contribution to journal › Review article › peer-review

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