Direct cyclic carbonate synthesis from CO2 and diol over carboxylation/hydration cascade catalyst of CeO2 with 2-cyanopyridine

Masayoshi Honda; Masazumi Tamura; Kenji Nakao; Kimihito Suzuki; Yoshinao Nakagawa; Keiichi Tomishige

doi:10.1021/cs500301d

Direct cyclic carbonate synthesis from CO₂ and diol over carboxylation/hydration cascade catalyst of CeO₂ with 2-cyanopyridine

Masayoshi Honda, Masazumi Tamura, Kenji Nakao, Kimihito Suzuki, Yoshinao Nakagawa, Keiichi Tomishige

ENG - Applied Chemistry

Research output: Contribution to journal › Review article › peer-review

139 Citations (Scopus)

Abstract

We first achieved direct synthesis of propylene carbonate from CO ₂ and 1,2-propanediol in excellent yield (>99%) using a carboxylation/hydration cascade catalyst of CeO₂ with 2-cyanopyridine. The catalyst system can be applied to syntheses of various cyclic carbonates, including 6-membered ring carbonates that are difficult to synthesize in high yields (62->99%).

Original language	English
Pages (from-to)	1893-1896
Number of pages	4
Journal	ACS Catalysis
Volume	4
Issue number	6
DOIs	https://doi.org/10.1021/cs500301d
Publication status	Published - 2014 Jun 6

Keywords

Cerium oxide
carbonate
carboxylation
hydration

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1021/cs500301d

Cite this

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title = "Direct cyclic carbonate synthesis from CO2 and diol over carboxylation/hydration cascade catalyst of CeO2 with 2-cyanopyridine",

abstract = "We first achieved direct synthesis of propylene carbonate from CO 2 and 1,2-propanediol in excellent yield (>99%) using a carboxylation/hydration cascade catalyst of CeO2 with 2-cyanopyridine. The catalyst system can be applied to syntheses of various cyclic carbonates, including 6-membered ring carbonates that are difficult to synthesize in high yields (62->99%).",

keywords = "Cerium oxide, carbonate, carboxylation, hydration",

author = "Masayoshi Honda and Masazumi Tamura and Kenji Nakao and Kimihito Suzuki and Yoshinao Nakagawa and Keiichi Tomishige",

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T1 - Direct cyclic carbonate synthesis from CO2 and diol over carboxylation/hydration cascade catalyst of CeO2 with 2-cyanopyridine

AU - Honda, Masayoshi

AU - Tamura, Masazumi

AU - Nakao, Kenji

AU - Suzuki, Kimihito

AU - Nakagawa, Yoshinao

AU - Tomishige, Keiichi

PY - 2014/6/6

Y1 - 2014/6/6

N2 - We first achieved direct synthesis of propylene carbonate from CO 2 and 1,2-propanediol in excellent yield (>99%) using a carboxylation/hydration cascade catalyst of CeO2 with 2-cyanopyridine. The catalyst system can be applied to syntheses of various cyclic carbonates, including 6-membered ring carbonates that are difficult to synthesize in high yields (62->99%).

AB - We first achieved direct synthesis of propylene carbonate from CO 2 and 1,2-propanediol in excellent yield (>99%) using a carboxylation/hydration cascade catalyst of CeO2 with 2-cyanopyridine. The catalyst system can be applied to syntheses of various cyclic carbonates, including 6-membered ring carbonates that are difficult to synthesize in high yields (62->99%).

KW - Cerium oxide

KW - carbonate

KW - carboxylation

KW - hydration

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U2 - 10.1021/cs500301d

DO - 10.1021/cs500301d

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EP - 1896

JO - ACS Catalysis

JF - ACS Catalysis

SN - 2155-5435

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