Direct condensation of functionalized sp3 carbons with formanilides for enamine synthesis using an in situ generated HMDS amide catalyst

Hiroshi Taneda; Kiyofumi Inamoto; Yoshinori Kondo

doi:10.1039/c4cc02228a

Direct condensation of functionalized sp³ carbons with formanilides for enamine synthesis using an in situ generated HMDS amide catalyst

Hiroshi Taneda, Kiyofumi Inamoto, Yoshinori Kondo

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The efficient synthesis of functionalized enamines including β-enaminoesters was effectively accomplished by the direct condensation of functionalized sp³ carbanions such as acetates with formamides using in situ generated HMDS base from catalytic cesium fluoride and stoichiometric tristrimethylsilylamine.

Original language	English
Pages (from-to)	6523-6525
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	49
DOIs	https://doi.org/10.1039/c4cc02228a
Publication status	Published - 2014 May 22

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The efficient synthesis of functionalized enamines including β-enaminoesters was effectively accomplished by the direct condensation of functionalized sp3 carbanions such as acetates with formamides using in situ generated HMDS base from catalytic cesium fluoride and stoichiometric tristrimethylsilylamine.",

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