Direct Catalytic Synthesis of N-Arylcarbamates from CO2, Anilines and Alcohols

Masazumi Tamura, Ayaka Miura, Masayoshi Honda, Yu Gu, Yoshinao Nakagawa, Keiichi Tomishige

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The direct catalytic synthesis of carbamates from CO2, amines and methanol was achieved by controlling both the reaction equilibrium and the reactivity of the three components. The combination of CeO2 and 2-cyanopyridine was an effective catalyst, providing various carbamates including N-arylcarbamates in high selectivities.

Original languageEnglish
Pages (from-to)4835-4839
Number of pages5
JournalChemCatChem
Volume10
Issue number21
DOIs
Publication statusPublished - 2018 Nov 7

Keywords

  • arylamine
  • carbamate
  • carbon dioxide
  • ceria
  • heterogeneous catalyst

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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