Direct Catalytic Synthesis of N-Arylcarbamates from CO2, Anilines and Alcohols

Masazumi Tamura; Ayaka Miura; Masayoshi Honda; Yu Gu; Yoshinao Nakagawa; Keiichi Tomishige

doi:10.1002/cctc.201801443

Direct Catalytic Synthesis of N-Arylcarbamates from CO₂, Anilines and Alcohols

Masazumi Tamura, Ayaka Miura, Masayoshi Honda, Yu Gu, Yoshinao Nakagawa, Keiichi Tomishige

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The direct catalytic synthesis of carbamates from CO₂, amines and methanol was achieved by controlling both the reaction equilibrium and the reactivity of the three components. The combination of CeO₂ and 2-cyanopyridine was an effective catalyst, providing various carbamates including N-arylcarbamates in high selectivities.

Original language	English
Pages (from-to)	4835-4839
Number of pages	5
Journal	ChemCatChem
Volume	10
Issue number	21
DOIs	https://doi.org/10.1002/cctc.201801443
Publication status	Published - 2018 Nov 7

Keywords

arylamine
carbamate
carbon dioxide
ceria
heterogeneous catalyst

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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AU - Miura, Ayaka

AU - Honda, Masayoshi

AU - Gu, Yu

AU - Nakagawa, Yoshinao

AU - Tomishige, Keiichi

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KW - carbamate

KW - carbon dioxide

KW - ceria

KW - heterogeneous catalyst

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