Direct analysis of hydrogen transfer reaction from p-benzosemiquinone radical to p-benzoquinone by time-resolved CIDNP method

T. Aizawa, Y. Araki, K. Shindo, K. Maeda, T. Azumi

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The rate constant of the hydrogen transfer reaction from p-benzosemiquinone radical to p-benzoquinone was measured by the time-resolved CIDNP technique. The time dependence of the CIDNP intensity of the products, p-benzoquinone and p-hydrobenzoquinone, can be simulated by kinetic treatment. From the simulation, the rate constant of the hydrogen transfer is obtained.

Original languageEnglish
Pages (from-to)1443-1450
Number of pages8
JournalSpectrochimica Acta Part A: Molecular Spectroscopy
Volume50
Issue number8-9
DOIs
Publication statusPublished - 1994

ASJC Scopus subject areas

  • Engineering(all)

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