Dinuclear palladium complex with a bridging dialkylsilylene ligand

Chieko Watanabe, Takeaki Iwamoto, Chizuko Kabuto, Mitsuo Kira

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

A novel dinuclear palladium complex with one bridging dialkylsilylene ligand 6 was synthesized by the reaction of isolable dialkylsilylene 7 (R 2Si:) with two equiv of bis(tricyclohexyl)-phosphinepalladium (8). Complex 6 as a prototypical dipalladasilacyclopropane reacts with molecular hydrogen to give dihydrosilane 10 (R2SiH2) together with 8 and metallic palladium.

Original languageEnglish
Pages (from-to)284-285
Number of pages2
JournalChemistry Letters
Volume36
Issue number2
DOIs
Publication statusPublished - 2007 Feb 5

ASJC Scopus subject areas

  • Chemistry(all)

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