Dimethyl carbonate synthesis by oxidative carbonylation on activated carbon supported CuCl2 catalysts: Catalytic properties and structural change

Keiichi Tomishige; Tomohiro Sakaihori; Shin Ichiro Sakai; Kaoru Fujimoto

doi:10.1016/S0926-860X(98)00386-X

Dimethyl carbonate synthesis by oxidative carbonylation on activated carbon supported CuCl₂ catalysts: Catalytic properties and structural change

Keiichi Tomishige, Tomohiro Sakaihori, Shin Ichiro Sakai, Kaoru Fujimoto

Research output: Contribution to journal › Article › peer-review

98 Citations (Scopus)

Abstract

Catalytic properties of CuCl₂ catalysts supported on activated carbon in the synthesis of dimethyl carbonate by oxidative carbonylation of methanol were investigated. Structural changes during the reaction were studied. It was suggested that dimethyl carbonate formation rate is strongly related to Cl/Cu ratio and CO formation rate is higher on the catalyst with Cu oxychloride than on that with Cu-Cl-OH.

Original language	English
Pages (from-to)	95-102
Number of pages	8
Journal	Applied Catalysis A: General
Volume	181
Issue number	1
DOIs	https://doi.org/10.1016/S0926-860X(98)00386-X
Publication status	Published - 1999 May 3
Externally published	Yes

Keywords

Activated carbon supported CuCl catalyst
Catalyst structure
Dimethyl carbonate synthesis
Oxidative carbonylation of methanol

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology

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abstract = "Catalytic properties of CuCl2 catalysts supported on activated carbon in the synthesis of dimethyl carbonate by oxidative carbonylation of methanol were investigated. Structural changes during the reaction were studied. It was suggested that dimethyl carbonate formation rate is strongly related to Cl/Cu ratio and CO formation rate is higher on the catalyst with Cu oxychloride than on that with Cu-Cl-OH.",

keywords = "Activated carbon supported CuCl catalyst, Catalyst structure, Dimethyl carbonate synthesis, Oxidative carbonylation of methanol",

author = "Keiichi Tomishige and Tomohiro Sakaihori and Sakai, {Shin Ichiro} and Kaoru Fujimoto",

year = "1999",

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T2 - Catalytic properties and structural change

AU - Tomishige, Keiichi

AU - Sakaihori, Tomohiro

AU - Sakai, Shin Ichiro

AU - Fujimoto, Kaoru

PY - 1999/5/3

Y1 - 1999/5/3

N2 - Catalytic properties of CuCl2 catalysts supported on activated carbon in the synthesis of dimethyl carbonate by oxidative carbonylation of methanol were investigated. Structural changes during the reaction were studied. It was suggested that dimethyl carbonate formation rate is strongly related to Cl/Cu ratio and CO formation rate is higher on the catalyst with Cu oxychloride than on that with Cu-Cl-OH.

AB - Catalytic properties of CuCl2 catalysts supported on activated carbon in the synthesis of dimethyl carbonate by oxidative carbonylation of methanol were investigated. Structural changes during the reaction were studied. It was suggested that dimethyl carbonate formation rate is strongly related to Cl/Cu ratio and CO formation rate is higher on the catalyst with Cu oxychloride than on that with Cu-Cl-OH.

KW - Activated carbon supported CuCl catalyst

KW - Catalyst structure

KW - Dimethyl carbonate synthesis

KW - Oxidative carbonylation of methanol

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