Dielectric anisotropy of a homochiral trinuclear nickel(II) complex

Da Wei Fu, Yu Mei Song, Guo Xi Wang, Qiong Ye, Ren Gen Xiong, Tomoyuki Akutagawa, Takayoshi Nakamura, Philip Wai Hong Chan, Songping D. Huang

Research output: Contribution to journalArticlepeer-review

172 Citations (Scopus)

Abstract

Hydrothermal reaction of (S)-1,1′1″-2,4,6-trimethylbenzene-1,3,5-triyl-tris(methylene)-tris-pyrrolidine-2-carboxylic acid (TBPLA) with Ni(ClO4)2·6H2O gave pale green block crystals of 1. X-ray crystal structure analysis showed the complex to be a trinuclear descrete homochiral molecule with each Ni center sitting in distorted octahedron geometries. Anisotropic permittivity measurements reveal that 1 exhibits huge dielectric anisotropy along its three different crystal axes that is ca. 3.5 times of εr (E//c)/εr (E//b) with temperature and frequency independence.

Original languageEnglish
Pages (from-to)5346-5347
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number17
DOIs
Publication statusPublished - 2007 May 2
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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