DIBALH-mediated reductive ring-expansion reaction of cyclic ketoxime

Taku Imaizumi, Kentaro Okano, Hidetoshi Tokuyama

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The article discusses DIBALH-mediated reductive ring-expansion reaction of cyclic ketoxime. In contrast to the Beckmann rearrangement, the two possible geometries of the oxime C–N double bond can give exclusively an aromatic secondary amine in the presented method.

Original languageEnglish
JournalOrganic Syntheses
Volume93
DOIs
Publication statusPublished - 2016 Jan 1

Keywords

  • 1-indanone oxime
  • Beckmann rearrangement
  • Chemical-specific hazards
  • DIBALH
  • Mersicarpine
  • Reductive ring-expansion reaction
  • Ring-expansion reaction
  • Tetrahydroquinoline

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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