Diastereoselective and enantioselective catalysis of the carbonyl-ene reaction with fluoral

Koichi Mikami, Tomoko Yajima, Masahiro Terada, Etsuko Kato, Masamichi Maruta

Research output: Contribution to journalArticlepeer-review

40 Citations (Scopus)

Abstract

The chiral titanium complex-catalyzed carbonyl-ene reaction with fluoral is shown to serve as an efficient route for the syn-diastereoselective and enantioselective synthesis of CF3-substituted compounds of biological and synthetic importance.

Original languageEnglish
Pages (from-to)1087-1090
Number of pages4
JournalTetrahedron: Asymmetry
Volume5
Issue number6
DOIs
Publication statusPublished - 1994 Jun
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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