Diastereomer liquid crystalline CF3 molecules: conformational probe for (anti)ferroelectricity and spontaneous resolution of the racemates

Koichi Mikami; Tomoko Yajima; Jun Kojima; Masahiro Terada; Susumu Kawauchi; Hiroko Shirasaki; Kenji Okuyama; Yoshiichi Suzuki; Ichiro Kobayashi; Yoichi Takanishi; Hideo Takezoe

doi:10.1080/10587250008023864

Diastereomer liquid crystalline CF₃ molecules: conformational probe for (anti)ferroelectricity and spontaneous resolution of the racemates

Koichi Mikami, Tomoko Yajima, Jun Kojima, Masahiro Terada, Susumu Kawauchi, Hiroko Shirasaki, Kenji Okuyama, Yoshiichi Suzuki, Ichiro Kobayashi, Yoichi Takanishi, Hideo Takezoe

Research output: Contribution to journal › Conference article › peer-review

4 Citations (Scopus)

Abstract

Diastereomeric α- or β-CF₃ liquid crystalline molecules (LCs) with double stereogenic centers are reported as conformational probes for the bent (L-shape) conformation of antiferroelectric LCs. The diastereomeric LCs show their intriguing features that the racemic composition for both diastereomers self-assemble into the enantiomeric domain spontaneously to exhibit the electrooptic switching.

Original language	English
Pages (from-to)	41-49
Number of pages	9
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	346
DOIs	https://doi.org/10.1080/10587250008023864
Publication status	Published - 2000 Jan 1
Externally published	Yes
Event	Anglo-Japanese Seminar on Liquid Crystals'99 - Nara, Jpn Duration: 1999 May 26 → 1999 May 28

ASJC Scopus subject areas

Condensed Matter Physics

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Mikami, K., Yajima, T., Kojima, J., Terada, M., Kawauchi, S., Shirasaki, H., Okuyama, K., Suzuki, Y., Kobayashi, I., Takanishi, Y., & Takezoe, H. (2000). Diastereomer liquid crystalline CF₃ molecules: conformational probe for (anti)ferroelectricity and spontaneous resolution of the racemates. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 346, 41-49. https://doi.org/10.1080/10587250008023864

Diastereomer liquid crystalline CF₃ molecules : conformational probe for (anti)ferroelectricity and spontaneous resolution of the racemates. / Mikami, Koichi; Yajima, Tomoko; Kojima, Jun et al.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 346, 01.01.2000, p. 41-49.

Research output: Contribution to journal › Conference article › peer-review

Mikami, K, Yajima, T, Kojima, J, Terada, M, Kawauchi, S, Shirasaki, H, Okuyama, K, Suzuki, Y, Kobayashi, I, Takanishi, Y & Takezoe, H 2000, 'Diastereomer liquid crystalline CF₃ molecules: conformational probe for (anti)ferroelectricity and spontaneous resolution of the racemates', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 346, pp. 41-49. https://doi.org/10.1080/10587250008023864

Mikami K, Yajima T, Kojima J, Terada M, Kawauchi S, Shirasaki H et al. Diastereomer liquid crystalline CF₃ molecules: conformational probe for (anti)ferroelectricity and spontaneous resolution of the racemates. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 2000 Jan 1;346:41-49. doi: 10.1080/10587250008023864

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abstract = "Diastereomeric α- or β-CF3 liquid crystalline molecules (LCs) with double stereogenic centers are reported as conformational probes for the bent (L-shape) conformation of antiferroelectric LCs. The diastereomeric LCs show their intriguing features that the racemic composition for both diastereomers self-assemble into the enantiomeric domain spontaneously to exhibit the electrooptic switching.",

author = "Koichi Mikami and Tomoko Yajima and Jun Kojima and Masahiro Terada and Susumu Kawauchi and Hiroko Shirasaki and Kenji Okuyama and Yoshiichi Suzuki and Ichiro Kobayashi and Yoichi Takanishi and Hideo Takezoe",

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AU - Mikami, Koichi

AU - Yajima, Tomoko

AU - Kojima, Jun

AU - Terada, Masahiro

AU - Kawauchi, Susumu

AU - Shirasaki, Hiroko

AU - Okuyama, Kenji

AU - Suzuki, Yoshiichi

AU - Kobayashi, Ichiro

AU - Takanishi, Yoichi

AU - Takezoe, Hideo

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AB - Diastereomeric α- or β-CF3 liquid crystalline molecules (LCs) with double stereogenic centers are reported as conformational probes for the bent (L-shape) conformation of antiferroelectric LCs. The diastereomeric LCs show their intriguing features that the racemic composition for both diastereomers self-assemble into the enantiomeric domain spontaneously to exhibit the electrooptic switching.

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Diastereomer liquid crystalline CF₃ molecules: conformational probe for (anti)ferroelectricity and spontaneous resolution of the racemates

Abstract

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