Development of single-component molecular metals based on extended-TTF dithiolate ligands

A. Kobayashi, W. Suzuki, E. Fujiwara, H. Tanaka, Y. Fujishiro, E. Nishibori, M. Takata, M. Sakata, Y. Okanao, H. Kobayashi

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

The novel nickel complex with the extended-TTF dithiolate ligand [Ni(tmdt)2] (tmdt2= trimethylenedithiotetrathiafulvalenedithiolate) is the first three-dimensional single-component molecular metal. Structures and physical properties of analogous single-component molecular conductors [Ni(dmdt)2] (dmdt2-=dimethyltetrathiafulvalenedithiolate), [Ni(codt)2] (codt2-=ethylenedioxytetrathiafulvalenedithiolate) and [Pd(C3-tdt)2-] [(C3-tdt)2-= dipropylthiotetrathiafulvalenedithiolate] were examined. The structure of [Au(tmdt)2] was determined by synchrotron radiation powder diffraction experiments and the MEM/Rietveld analysis. The single-component paramagnetic molecule [Cu(dmdt)2] was also studied to clarify the possibility of single-component magnetic molecular conductors.

Original languageEnglish
Pages (from-to)511-513
Number of pages3
JournalSynthetic Metals
Volume135-136
DOIs
Publication statusPublished - 2003 Apr 4
Externally publishedYes

Keywords

  • Diffraction and scattering
  • Electrocrystallization
  • Organic conductors based on radical cation and/or anion salts
  • X-ray emission

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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