Abstract
We constructed a single-crystal synchrotron X-ray diffraction system to precisely study the structure under hydrostatic pressure conditions at low temperatures and applied it to a study on the phase transition phenomena of a Cd-Yb periodic approximant and a Cd-Yb quasicrystal. Four phases were newly observed for the 1/1 approximant crystal in a P-T range up to 5.2 GPa and down to 10 K. The innermost part of the atomic clusters of Cd4 tetrahedra exhibited various orientational ordering sensitively depending on pressure and temperature. High pressure diffraction measurements using a highly parallel synchrotron X-ray beam and a hydrostatically compressed single crystal enabled us to detect the weak diffractions due to the subtle structural changes.
Original language | English |
---|---|
Pages (from-to) | 2905-2911 |
Number of pages | 7 |
Journal | Philosophical Magazine |
Volume | 87 |
Issue number | 18-21 |
DOIs | |
Publication status | Published - 2007 Jul |
Externally published | Yes |
ASJC Scopus subject areas
- Condensed Matter Physics