Deuterium Migration Mechanism in Chiral Thiolactam Formation by Neutron Diffraction Analysis

Takaaki Hosoya, Hidehiro Uekusa, Yuji Ohashi, Takashi Ohhara, Hiroyuki Kimura, Yukio Noda

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The single-crystal neutron diffraction revealed that in the process of photo-induced β-thiolactam formation from N,N-dibenzyl-1- cyclohexenecarbothioamide a deuterium atom bonded to the benzyl carbon atom is transferred to the intramolecular cyclohexene carbon to occupy the equatorial position of the produced cyclohexyl ring.

Original languageEnglish
Pages (from-to)742-743
Number of pages2
JournalChemistry Letters
Volume32
Issue number8
DOIs
Publication statusPublished - 2003 Aug 5

ASJC Scopus subject areas

  • Chemistry(all)

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