Abstract
The activation parameters were determined for the permanent allylic rearrangement (PAR) in five organoboranes of allylic type by means of complete line shape analysis for the dynamic NMR spectra. The introduction of the second boron atom into the allylborane molecule leads to a significant decrease in the activation barrier of the PAR.
| Original language | English |
|---|---|
| Pages (from-to) | 127-132 |
| Number of pages | 6 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 424 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 1992 Feb 11 |
| Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Cite this
Bubnov, Y. N., Gurskii, M. E., Gridnev, I. D., Ignatenko, A. V., Ustynyuk, Y. A., & Mstislavsky, V. I. (1992). Determination of the activation parameters of permanent allylic rearrangement in allyl- and methallylboranes and in 1,1-bis(dipropylborylmethyl)ethylene by dynamic NMR spectroscopy. Journal of Organometallic Chemistry, 424(2), 127-132. https://doi.org/10.1016/0022-328X(92)83142-5