Design of Janus nanoparticles with atomic precision: Tungsten-doped gold nanostructures

Qiang Sun, Qian Wang, Puru Jena, Yoshiyuki Kawazoe

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Janus nanoparticles, characterized by their anisotropic structure and interactions, have added a new dimension to nanoscience because of their potential applications in biomedicine, sensors, catalysis, and assembled materials. The technological applications of these nanoparticles, however, have been limited as the current chemical, physical, and biosynthetic methods lack sufficient size and shape selectivity. We report a technique where gold clusters doped with tungsten can serve as a seed that facilitates the natural growth of anisotropic nanostructures whose size and shape can be controlled with atomic precision. Using ab initio simulated annealing and molecular dynamics calculations on Aun W (n > 12) clusters, we discovered that the WΑu12 cage cluster forms a very stable core with the remaining Au atoms forming patchy structures on its surface. The anisotropic geometry gives rise to anisotropies in vibrational spectra, charge distributions, electronic structures, and reactivity, thus making it useful to have dual functionalities. In particular, the core - patch structure is shown to possess a hydrophilic head and a hydrophobic tail. The WΑu12 clusters can also be used as building blocks of a nanoring with novel properties.

Original languageEnglish
Pages (from-to)341-347
Number of pages7
JournalACS Nano
Volume2
Issue number2
DOIs
Publication statusPublished - 2008 Feb 1

Keywords

  • Janus structure
  • Magic cluster
  • Multifunction
  • Nanoanisotropy
  • Stability

ASJC Scopus subject areas

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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