Dephosphorization Reaction of Chromium Containing Molten Iron by CaO-based Flux

Shin Ya Kitamura, Hiroyuki Aoki, Kazuo Okohira

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Dephosphorization tests of chromium containing molten iron by CaO-based flux have been carried out by an induction furnace. The following results were obtained: (1) When the carbon content in metal was high enough, chromium containing molten iron was able to be dephosphorized by CaO-CaF2-FeO flux. In this case, oxygen partial pressure at the slag and metal interface was calculated to be about 10-12Pa. (2) The higher ratio of CaF2/(CaO + CaF2) and of CaO/O in flux were effective for the dephosphorization without the oxidization of chromium. Based on these results, 200 ton scale industrial tests have been carried out by the hot metal pretreatment station at Yawata Works. By the combination of the flux injection method and the oxygen top blowing method, it was clarified that the dephosphorization without chromium oxidation and the suppression of temperature drop were able to be achieved simultaneously.

Original languageEnglish
Pages (from-to)401-407
Number of pages7
JournalIsij International
Volume34
Issue number5
DOIs
Publication statusPublished - 1994

Keywords

  • activity coefficient
  • dephosphorization
  • hot metal pretreatment
  • mass transfer rate
  • oxygen gas
  • stainless steel

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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