Abstract
In this study, we report densities and thermal conductivities for 1-butyl-3-methylimidazolium tetrafluoroborate + methanol mixtures. The densities were measured using a vibrating tube densimeter over the temperature range 293–333 K and at pressures up to 20 MPa. The expanded uncertainty in the density measurements was 0.22% (k = 2). The experimental values were correlated with a Tait equation with an average absolute deviation of 0.10%. The transient short hot-wire method was used to measure the thermal conductivities over the temperature range 295–335 K at 0.1 MPa. The expanded uncertainty in the thermal conductivity measurements was 4.4%. The thermal conductivities of the 1-butyl-3-methylimidazolium tetrafluoroborate + methanol mixtures increased in an approximately quadratically with increasing methanol mass fraction. The experimental values were correlated with a Jamieson equation with an average absolute deviation of 0.24%.
Original language | English |
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Pages (from-to) | 299-310 |
Number of pages | 12 |
Journal | High Temperatures - High Pressures |
Volume | 47 |
Issue number | 4 |
Publication status | Published - 2018 |
Keywords
- 1-Butyl-3-methylimidazolium tetrafluoroborate
- Density
- High pressure
- Ionic liquid
- Methanol
- Thermal conductivity
- Transient short hot-wire
ASJC Scopus subject areas
- Condensed Matter Physics
- Mechanics of Materials
- Physical and Theoretical Chemistry