Demonstration of real biomass gasification drastically promoted by effective catalyst

Mohammad Asadullah, Tomohisa Miyazawa, Shin Ichi Ito, Kimio Kunimori, Keiichi Tomishige

Research output: Contribution to journalArticlepeer-review

105 Citations (Scopus)

Abstract

The gasification of cedar wood using highly efficient Rh/CeO2/SiO2(60) catalyst and air as a gasifying agent has been investigated in a continuous feeding fluidized bed gasifier at low temperatures (823-973 K). Regarding the carbon conversion and syngas formation, Rh/CeO2/SiO2(60) catalyst exhibited much better results than conventional Ni and dolomite catalysts, and the non-catalytic process. The performance of Rh/CeO2/SiO2 was very dependent on the loading amount of CeO2; in this case 60% CeO2 on SiO2 was the most suitable. In the case of the most effective catalyst, Rh/CeO2/SiO2(60), no severe deactivation was observed even in the longer reaction time (4 h). The catalyst developed in the cellulose gasification is also applicable to the gasification of real biomass (wood powder).

Original languageEnglish
Pages (from-to)103-116
Number of pages14
JournalApplied Catalysis A: General
Volume246
Issue number1
DOIs
Publication statusPublished - 2003 Jun 25
Externally publishedYes

Keywords

  • Biomass
  • Catalytic gasification
  • Cerium oxide
  • Fluidized bed
  • Rhodium
  • Synthesis gas

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Fingerprint Dive into the research topics of 'Demonstration of real biomass gasification drastically promoted by effective catalyst'. Together they form a unique fingerprint.

Cite this