Dehydrogenative coupling of monohydrosilanes mediated by (2-phosphinoethyl)silylrhodium(I) complex

Masaaki Okazaki, Shin Ohshitanai, Hiromi Tobita, Hiroshi Ogino

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Treatment of HSiMe2Ph with a square-planar rhodium(I) complex Rh[(κ2-Si,P)-Me2SiCH2CH 2PPh2](PMe3)2 gave rise to selective dehydrogenative coupling of hydrosilanes to afford (SiMe2Ph)2 and RhH2[(κ2-Si,P)-Me2SiCH2CH 2PPh2](PMe3)2.

Original languageEnglish
Pages (from-to)952-953
Number of pages2
JournalChemistry Letters
Issue number10
DOIs
Publication statusPublished - 2001 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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