Degradation of phenol by the collapse of microbubbles

Pan Li, Masayoshi Takahashi, Kaneo Chiba

Research output: Contribution to journalArticlepeer-review

97 Citations (Scopus)

Abstract

This study focuses on the application of microbubble collapse technique to the wastewater treatment. We have verified that collapsing air microbubbles lead to the decomposition of phenol, a common pollutant. A reduction in phenol of ∼60% was observed during a 2-h test period when air was used as the microbubble source. We have also studied the dependence of phenol degradation on the pH of the solution and the type of gas within the microbubbles. The pseudo-first-order kinetic constant for the degradation of phenol, k, increased linearly with the concentration of H+ in solution. The use of oxygen microbubbles gave rise to the highest k value (1.6 h-1) measured. It is suggested that hydroxyl radicals play an important role in the phenol decomposition process. The acquired information would be useful for the future application of microbubbles in the field of wastewater treatment.

Original languageEnglish
Pages (from-to)1371-1375
Number of pages5
JournalChemosphere
Volume75
Issue number10
DOIs
Publication statusPublished - 2009 Jun
Externally publishedYes

Keywords

  • Collapse
  • Free radical
  • Microbubble
  • Shrinkage
  • Wastewater treatment

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry
  • Chemistry(all)
  • Pollution
  • Health, Toxicology and Mutagenesis

Fingerprint

Dive into the research topics of 'Degradation of phenol by the collapse of microbubbles'. Together they form a unique fingerprint.

Cite this