Decomposition of mono-, di-And tri-chlorobenzene by using basic molten salts

Osamu Takeda, Daisuke Aoki, Yasufumi Yokka, Tsutomu Yamamura, Yuzuru Sato

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The decomposition of simple chlorinated organic compounds comprising benzene derivatives (mono, di and tri-chlorobenzenes) as the imitation substance of polychlorobiphenyls (PCBs) was investigated by using basic molten salts in order to establish a safe, simple and highly efficient decomposition process for PCBs. Chlorobenzen liquid or the solution was injected into basic molten salts (KOH-K 2CO 3 or NaOH-Na 2CO 3) at 573-973 K with imitation air, and the residual concentration of chlorobenzenes in the exhaust was measured after the decomposition treatment. The decomposition efficiency reached to very high of 99.9999% in an optimum condition. The decomposition efficiencies of chlorobenzenes were affected by the flow rate of the air and the initial concentration of chlorobenzen in the gas mixture. The complete destruction for benzene derivatives required excess oxygen condition.

Original languageEnglish
Pages (from-to)1705-1711
Number of pages7
JournalIsij International
Volume52
Issue number9
DOIs
Publication statusPublished - 2012

Keywords

  • Basic molten salts
  • Chlorinated organic compounds
  • Chlorobenzen
  • Decomposition
  • PCB
  • Waste treatment

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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