Dearomative cycloadditions of a silylene with pyrazine and quinoxaline

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2 Citations (Scopus)

Abstract

The dearomative cycloaddition of a silylene with pyrazine provides a disilicon and dinitrogen analogue of cis,cis,trans-1,3,6-cyclooctatriene 2 as a purple solid. Compound 2 has a twisted and pyramidalised trans-alkene moiety. The HOMO → LUMO [n(N) → π∗(NC-CN)] transition band of 2 appeared at 525 nm in a hexane solution.

Original languageEnglish
Pages (from-to)11317-11321
Number of pages5
JournalDalton Transactions
Volume47
Issue number33
DOIs
Publication statusPublished - 2018 Jan 1

ASJC Scopus subject areas

  • Inorganic Chemistry

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