Cyanide-bridged Fe(III)-Mn(III) chain with metamagnetic properties and significant magnetic anisotropy

Shi Wang, Marilena Ferbinteanu, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

47 Citations (Scopus)

Abstract

The assembling of [Mn(5-MeOsalen)(H2O)]+ and [(Tp)Fe(CN)3]- affords the one-dimensional zigzag chain [(Tp)Fe(CN)3Mn(5-MeOsalen)·2CH3OH]n [1; Tp- = hydrotris(pyrazolyl)borate and 5-MeOsalen2- = N,N′-ethylenebis(5-methoxysalicylideneiminate)]. The corroborated experimental and ab initio data indicate ferromagnetic Fe(III)-Mn(III) couplings and D < 0 anisotropy on Mn-(III). The field-induced metamagnetic behavior is due to interchain effects.

Original languageEnglish
Pages (from-to)610-612
Number of pages3
JournalInorganic chemistry
Volume46
Issue number3
DOIs
Publication statusPublished - 2007 Feb 5
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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