Cyanide-bridged Fe(III)-Mn(III) chain with metamagnetic properties and significant magnetic anisotropy

Shi Wang; Marilena Ferbinteanu; Masahiro Yamashita

doi:10.1021/ic061681n

Cyanide-bridged Fe(III)-Mn(III) chain with metamagnetic properties and significant magnetic anisotropy

Shi Wang, Marilena Ferbinteanu, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

The assembling of [Mn(5-MeOsalen)(H₂O)]⁺ and [(Tp)Fe(CN)₃]^- affords the one-dimensional zigzag chain [(Tp)Fe(CN)₃Mn(5-MeOsalen)·2CH₃OH]_n [1; Tp^- = hydrotris(pyrazolyl)borate and 5-MeOsalen^2- = N,N′-ethylenebis(5-methoxysalicylideneiminate)]. The corroborated experimental and ab initio data indicate ferromagnetic Fe(III)-Mn(III) couplings and D < 0 anisotropy on Mn-(III). The field-induced metamagnetic behavior is due to interchain effects.

Original language	English
Pages (from-to)	610-612
Number of pages	3
Journal	Inorganic chemistry
Volume	46
Issue number	3
DOIs	https://doi.org/10.1021/ic061681n
Publication status	Published - 2007 Feb 5

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Cyanide-bridged Fe(III)-Mn(III) chain with metamagnetic properties and significant magnetic anisotropy",

abstract = "The assembling of [Mn(5-MeOsalen)(H2O)]+ and [(Tp)Fe(CN)3]- affords the one-dimensional zigzag chain [(Tp)Fe(CN)3Mn(5-MeOsalen)·2CH3OH]n [1; Tp- = hydrotris(pyrazolyl)borate and 5-MeOsalen2- = N,N′-ethylenebis(5-methoxysalicylideneiminate)]. The corroborated experimental and ab initio data indicate ferromagnetic Fe(III)-Mn(III) couplings and D < 0 anisotropy on Mn-(III). The field-induced metamagnetic behavior is due to interchain effects.",

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T1 - Cyanide-bridged Fe(III)-Mn(III) chain with metamagnetic properties and significant magnetic anisotropy

AU - Wang, Shi

AU - Ferbinteanu, Marilena

AU - Yamashita, Masahiro

PY - 2007/2/5

Y1 - 2007/2/5

N2 - The assembling of [Mn(5-MeOsalen)(H2O)]+ and [(Tp)Fe(CN)3]- affords the one-dimensional zigzag chain [(Tp)Fe(CN)3Mn(5-MeOsalen)·2CH3OH]n [1; Tp- = hydrotris(pyrazolyl)borate and 5-MeOsalen2- = N,N′-ethylenebis(5-methoxysalicylideneiminate)]. The corroborated experimental and ab initio data indicate ferromagnetic Fe(III)-Mn(III) couplings and D < 0 anisotropy on Mn-(III). The field-induced metamagnetic behavior is due to interchain effects.

AB - The assembling of [Mn(5-MeOsalen)(H2O)]+ and [(Tp)Fe(CN)3]- affords the one-dimensional zigzag chain [(Tp)Fe(CN)3Mn(5-MeOsalen)·2CH3OH]n [1; Tp- = hydrotris(pyrazolyl)borate and 5-MeOsalen2- = N,N′-ethylenebis(5-methoxysalicylideneiminate)]. The corroborated experimental and ab initio data indicate ferromagnetic Fe(III)-Mn(III) couplings and D < 0 anisotropy on Mn-(III). The field-induced metamagnetic behavior is due to interchain effects.

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