Abstract
The assembling of [Mn(5-MeOsalen)(H2O)]+ and [(Tp)Fe(CN)3]- affords the one-dimensional zigzag chain [(Tp)Fe(CN)3Mn(5-MeOsalen)·2CH3OH]n [1; Tp- = hydrotris(pyrazolyl)borate and 5-MeOsalen2- = N,N′-ethylenebis(5-methoxysalicylideneiminate)]. The corroborated experimental and ab initio data indicate ferromagnetic Fe(III)-Mn(III) couplings and D < 0 anisotropy on Mn-(III). The field-induced metamagnetic behavior is due to interchain effects.
Original language | English |
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Pages (from-to) | 610-612 |
Number of pages | 3 |
Journal | Inorganic chemistry |
Volume | 46 |
Issue number | 3 |
DOIs | |
Publication status | Published - 2007 Feb 5 |
Externally published | Yes |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry