Cyanide-bridged decanuclear cobalt-iron cage

Takuya Shiga, Tamaki Tetsuka, Kanae Sakai, Yoshihiro Sekine, Masayuki Nihei, Graham N. Newton, Hiroki Oshio

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ETCST) behavior between Co III low-spin-NC-FeII low-spin and CoII high-spin-NC-FeIII low-spin states, as confirmed by single-crystal X-ray, magnetic, and Mössbauer analyses.

Original languageEnglish
Pages (from-to)5899-5901
Number of pages3
JournalInorganic Chemistry
Volume53
Issue number12
DOIs
Publication statusPublished - 2014 Jun 16
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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