Crystallization of tungstenbronze phase and its inelastic light scattering in niobiophosphate-system glass

Yoshihiro Takahashi, Nobuhiro Fujie, Minoru Osada, Rie Ihara, Takumi Fujiwara

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

We prepared a niobiophosphate-glass-crystallizing tungstenbronze-type Ba2NaNb5O15 and measured elastic light scattering spectra in situ in the glass-ceramics fabrication regime. We found that the studied glass possesses a strong tendency for phase separation into Al2O3-P2O5 and Nb-rich regions prior to crystallization. It is suggested that the tungstenbronze phase crystallizes in the Nb-rich region separated from the supercooled liquid phase. This study demonstrated that in situ Raman spectroscopy is also useful for observing the phase-separation dynamics in glass.

Original languageEnglish
Title of host publicationElectroceramics in Japan XV
PublisherTrans Tech Publications Ltd
Pages306-309
Number of pages4
ISBN (Print)9783037857618
DOIs
Publication statusPublished - 2013 Jan 1
Event31st Electronics Division Meeting of the Ceramic Society of Japan - Tokyo, Japan
Duration: 2011 Oct 282011 Oct 29

Publication series

NameKey Engineering Materials
Volume566
ISSN (Print)1013-9826
ISSN (Electronic)1662-9795

Other

Other31st Electronics Division Meeting of the Ceramic Society of Japan
CountryJapan
CityTokyo
Period11/10/2811/10/29

Keywords

  • Crystallization
  • Glass
  • Inelastic light scattering
  • Phase transition
  • Tungstenbronze phase

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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  • Cite this

    Takahashi, Y., Fujie, N., Osada, M., Ihara, R., & Fujiwara, T. (2013). Crystallization of tungstenbronze phase and its inelastic light scattering in niobiophosphate-system glass. In Electroceramics in Japan XV (pp. 306-309). (Key Engineering Materials; Vol. 566). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/KEM.566.306