Crystalline two-dimensional domains of cyanine dyes at interfaces

S. Kirstein; H. Möhwald; Masatsugu Shimomura

doi:10.1016/0009-2614(89)85360-6

Crystalline two-dimensional domains of cyanine dyes at interfaces

S. Kirstein, H. Möhwald, Masatsugu Shimomura

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

The formation of two-dimensional crystalline J-aggregates of a negatively charged water-soluble cyanine dye at a monolayer of a dimethylammonium amphiphile is observed by fluorescence microscopy and spectroscopy. It is demonstrated that domain size and morphology and spectroscopic properties can be controlled via the surface layer. The formation of rod-shaped crystalline aggregates tightly bound to the surface layer is established. These domains are of uniform size and shape, and order due to long-rang electrostatic repulsion.

Original language	English
Pages (from-to)	303-308
Number of pages	6
Journal	Chemical Physics Letters
Volume	154
Issue number	4
DOIs	https://doi.org/10.1016/0009-2614(89)85360-6
Publication status	Published - 1989 Jan 27

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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abstract = "The formation of two-dimensional crystalline J-aggregates of a negatively charged water-soluble cyanine dye at a monolayer of a dimethylammonium amphiphile is observed by fluorescence microscopy and spectroscopy. It is demonstrated that domain size and morphology and spectroscopic properties can be controlled via the surface layer. The formation of rod-shaped crystalline aggregates tightly bound to the surface layer is established. These domains are of uniform size and shape, and order due to long-rang electrostatic repulsion.",

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T1 - Crystalline two-dimensional domains of cyanine dyes at interfaces

AU - Kirstein, S.

AU - Möhwald, H.

AU - Shimomura, Masatsugu

PY - 1989/1/27

Y1 - 1989/1/27

N2 - The formation of two-dimensional crystalline J-aggregates of a negatively charged water-soluble cyanine dye at a monolayer of a dimethylammonium amphiphile is observed by fluorescence microscopy and spectroscopy. It is demonstrated that domain size and morphology and spectroscopic properties can be controlled via the surface layer. The formation of rod-shaped crystalline aggregates tightly bound to the surface layer is established. These domains are of uniform size and shape, and order due to long-rang electrostatic repulsion.

AB - The formation of two-dimensional crystalline J-aggregates of a negatively charged water-soluble cyanine dye at a monolayer of a dimethylammonium amphiphile is observed by fluorescence microscopy and spectroscopy. It is demonstrated that domain size and morphology and spectroscopic properties can be controlled via the surface layer. The formation of rod-shaped crystalline aggregates tightly bound to the surface layer is established. These domains are of uniform size and shape, and order due to long-rang electrostatic repulsion.

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

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ER -

Crystalline two-dimensional domains of cyanine dyes at interfaces

Abstract

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