Crystal-to-crystal transformation of fishnet-like layered compounds: a self-locking structure with position-variable intercalated molecules

Masaki Nishio, Natsuko Motokawa, Hitoshi Miyasaka

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

Fishnet-like layered compounds comprising trifluoroacetate-bridged paddlewheel dimetal(ii, ii) complexes and 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) were crystalized with anthracene (ANT) molecules between their layers and crystallization solvents at their hexagonal columnar pores. These complexes undergo a solvent-release crystal-to-crystal transformation involving the migration of a portion of the ANT molecules from between the layers to the hexagonal pores, effectively locking the slidable layers.

Original languageEnglish
Pages (from-to)7618-7622
Number of pages5
JournalCrystEngComm
Volume17
Issue number40
DOIs
Publication statusPublished - 2015 Jul 24

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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