Crystal structure of TiBi2

Kei Watanabe; Hisanori Yamane

doi:10.1107/S2056989016012391

Crystal structure of TiBi₂

Kei Watanabe, Hisanori Yamane

Center for Exploration of New Inorganic Materials

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Black granular single crystals of monotitanium dibismuth, TiBi2, were synthesized by slow cooling of a mixture of Bi and Ti from 693-K. The title compound is isostructural with CuMg2 (orthorhombic Fddd symmetry). Ti atoms are located in square antiprisms of Bi atoms. The network of one type of Bi atom spirals along the a-axis direction while honeycomb layers of the other type of Bi atom spreading in the ab plane interlace one another.

Original language	English
Pages (from-to)	1254-1256
Number of pages	3
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	72
DOIs	https://doi.org/10.1107/S2056989016012391
Publication status	Published - 2016

Keywords

CuMg structure type
bismuth
crystal structure
titanium

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "Black granular single crystals of monotitanium dibismuth, TiBi2, were synthesized by slow cooling of a mixture of Bi and Ti from 693-K. The title compound is isostructural with CuMg2 (orthorhombic Fddd symmetry). Ti atoms are located in square antiprisms of Bi atoms. The network of one type of Bi atom spirals along the a-axis direction while honeycomb layers of the other type of Bi atom spreading in the ab plane interlace one another.",

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AU - Yamane, Hisanori

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AB - Black granular single crystals of monotitanium dibismuth, TiBi2, were synthesized by slow cooling of a mixture of Bi and Ti from 693-K. The title compound is isostructural with CuMg2 (orthorhombic Fddd symmetry). Ti atoms are located in square antiprisms of Bi atoms. The network of one type of Bi atom spirals along the a-axis direction while honeycomb layers of the other type of Bi atom spreading in the ab plane interlace one another.

KW - CuMg structure type

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KW - crystal structure

KW - titanium

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