TY - JOUR
T1 - Crystal structure of the cis-bis(3-tert-butyl-o-diiminobenzosemiquinonato)-platinum(II) complex
AU - Masuya-Suzuki, Atsuko
AU - Iki, Nobuhiko
N1 - Publisher Copyright:
© 2016 The Japan Society for Analytical Chemistry.
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2016
Y1 - 2016
N2 - A square-planar platinum(II) complex, cis-bis(3-tert-butyl-o-diiminobenzosemiquinonato)platinum(II), was synthesized and characterized by single-crystal X-ray diffraction. It crystalizes in the monoclinic space group P21/n and Z = 4 with the following cell parameters: a = 19.748(2)Å, b = 5.9608(7)Å, c = 22.948(3)Å, β = 113.4550(10)°, V = 2478.2(5)Å3. The aromatic ring of the ligand is distorted into two shorter and four longer C-C bonds, which are representative of a o-diiminobenzosemiquinonate radical ligand.
AB - A square-planar platinum(II) complex, cis-bis(3-tert-butyl-o-diiminobenzosemiquinonato)platinum(II), was synthesized and characterized by single-crystal X-ray diffraction. It crystalizes in the monoclinic space group P21/n and Z = 4 with the following cell parameters: a = 19.748(2)Å, b = 5.9608(7)Å, c = 22.948(3)Å, β = 113.4550(10)°, V = 2478.2(5)Å3. The aromatic ring of the ligand is distorted into two shorter and four longer C-C bonds, which are representative of a o-diiminobenzosemiquinonate radical ligand.
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U2 - 10.2116/xraystruct.32.41
DO - 10.2116/xraystruct.32.41
M3 - Article
AN - SCOPUS:84988336189
VL - 32
SP - 41
EP - 43
JO - X-ray Structure Analysis Online
JF - X-ray Structure Analysis Online
SN - 1883-3578
IS - 9
ER -