Crystal structure of the cis-bis(3-tert-butyl-o-diiminobenzosemiquinonato)-platinum(II) complex

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Abstract

A square-planar platinum(II) complex, cis-bis(3-tert-butyl-o-diiminobenzosemiquinonato)platinum(II), was synthesized and characterized by single-crystal X-ray diffraction. It crystalizes in the monoclinic space group P21/n and Z = 4 with the following cell parameters: a = 19.748(2)Å, b = 5.9608(7)Å, c = 22.948(3)Å, β = 113.4550(10)°, V = 2478.2(5)Å3. The aromatic ring of the ligand is distorted into two shorter and four longer C-C bonds, which are representative of a o-diiminobenzosemiquinonate radical ligand.

Original languageEnglish
Pages (from-to)41-43
Number of pages3
JournalX-ray Structure Analysis Online
Volume32
Issue number9
DOIs
Publication statusPublished - 2016

ASJC Scopus subject areas

  • Analytical Chemistry
  • Materials Chemistry

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