Crystal structure of hydrogen-bonded supramolecular crystals

Daisuke Ishii, Tomokazu Iyoda, Masaru Nakagawa

Research output: Contribution to conferencePaper

Abstract

Hydrogen-bonded supramolecular crystals were formed from amphoteric azopyridine carboxylic acid derivatives by sublimation. In this report, we carried out the structural analysis of the hydrogen-bonded supramolecular crystals and revealed C-H⋯O hydrogen bonds between a carboxy oxygen atom and a hydrogen atom bonded with a carbon atom neighboring on an electron-drawing group. It was found that the C-H⋯O hydrogen bonds played a role to stabilize the supramolecular crystals thermally.

Original languageEnglish
Number of pages1
Publication statusPublished - 2005 Dec 1
Externally publishedYes
Event54th SPSJ Symposium on Macromolecules - Yamagata, Japan
Duration: 2005 Sep 202005 Sep 22

Other

Other54th SPSJ Symposium on Macromolecules
CountryJapan
CityYamagata
Period05/9/2005/9/22

Keywords

  • C-H⋯O
  • Crystal structure
  • Hydrogen bond
  • Non-covalent bond
  • Thermal analysis
  • X-ray

ASJC Scopus subject areas

  • Engineering(all)

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  • Cite this

    Ishii, D., Iyoda, T., & Nakagawa, M. (2005). Crystal structure of hydrogen-bonded supramolecular crystals. Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.