Crystal structure of a supramolecular cation salt (adamantylammonium +)2(benzo[18]crown-6)2[Pd(dmit) 2]2-(acetone)2

Kazuya Kubo, Yin Nan Yan, Shin Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Single crystal of supramolecuar cation salt (adamantylammonium +)2(benzo[18]crown-6)2[Pd(dmit) 2]2-(- acetone)2 were synthesized by an electrochemical crystallization. In the crystal, two supramolecular cations and two acetones and one [Pd(dmit)2]2- dianion were crystallographically asymmetric. Molecular rotation of adamantyl groups was suggested from anisotropic thermal factors in the X-ray analysis at 173 K.

    Original languageEnglish
    Pages (from-to)206-209
    Number of pages4
    JournalInorganica Chimica Acta
    Volume404
    DOIs
    Publication statusPublished - 2013

    Keywords

    • Crystal structure
    • Electrochemical crystallization
    • Molecular motion
    • Pd-dithiolene complex
    • Supramolecular rotator

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

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