Crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethylheptazethrene

Sho Kamata, Sota Sato, Jishan Wu, Hiroyuki Isobe

    Research output: Contribution to journalArticlepeer-review

    2 Citations (Scopus)

    Abstract

    The title compound, C50H44, 1, was synthesized as a derivative of heptazethrene bearing two methyl and two tert-butylphenyl substituents, respectively, at the 1,9- and 7,15-positions. The asymmetric unit consists of one half of the molecule, which lies about an inversion centre. Albeit remotely located, the substituents contort the heptazethrene plane. The tert-butylphenyl substituents stand approximately perpendicular to the core plane, with a dihedral angle of 79.09(5)° between the phenalene ring system and the substituted benzene ring, and prevent direct intermolecular contacts of the heptazethrene cores.

    Original languageEnglish
    Pages (from-to)99-102
    Number of pages4
    JournalActa Crystallographica Section E: Crystallographic Communications
    Volume73
    DOIs
    Publication statusPublished - 2017

    Keywords

    • crystal structure
    • heptazethrene
    • substituent effect

    ASJC Scopus subject areas

    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics

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