Crystal structure and physical properties of a dithiolene complex crystal with adamantane supramolecular rotator

Yin Nan Yan, Kazuya Kubo, Shin Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)

    Abstract

    Supramolecular cation salt of adamantane rotator with a dithiolene complex, (fluoroadamantylammonium+)([18]-crown-6)[Ni(dmit)2]- (1) was synthesized. The fluorine atom of the adamantane unit showed a large thermal factor elongated latitudinally, suggesting molecular rotation in the solid state. Crystal 1 exhibited a large dielectric response by applying an AC field along the a axis.

    Original languageEnglish
    Pages (from-to)417-419
    Number of pages3
    JournalBulletin of the Chemical Society of Japan
    Volume87
    Issue number3
    DOIs
    Publication statusPublished - 2014

    ASJC Scopus subject areas

    • Chemistry(all)

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