Crystal structure and magnetic properties of a dinuclear high-spin iron(III) complex with face-to-face bis(salen)-type ligands

Ryuta Ishikawa, Brian K. Breedlove, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Synthesis and crystal structure of the dinuclear complex threo-[Fe III 2(saltab)(Him)4](ClO2) 2·2MeOH (1) {H4saltab = (2R,3S)-1,2,3,4- tetrakis(salicylideneamino)butane, a bis-(salen)-type Schiff base ligand, and Him = imidazole} are reported. The magnetic behavior of 1 showed that it was in a high-spin state over the whole temperature region.

Original languageEnglish
Pages (from-to)716-719
Number of pages4
JournalEuropean Journal of Inorganic Chemistry
Issue number5-6
DOIs
Publication statusPublished - 2013 Feb 1

Keywords

  • Crystal engineering
  • Iron
  • Magnetic properties
  • Schiff bases
  • Solid-state structures

ASJC Scopus subject areas

  • Inorganic Chemistry

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