Crystal structure and electrical conductivity of [NH4+][18-crown-6][Ni(dmit)2]3

Tomoyuki Akutagawa, T. Nakamura, T. Inabe, A. E. Underhill

Research output: Contribution to journalConference articlepeer-review

Abstract

The [NH4+][Ni(dmit)2]3 complex, containing a macrocyclic molecule of 18-crown-6-ether (18C6), was obtained as [NH4+[18C6][Ni(dmit)2]3. This salt showed semiconducting behaviour with room temperature conductivity of 0.4 Scm-1. The crystal is composed of segregated non-uniform stack of Ni(dmit)2 and isolated ion-captured cavity of [NH4+][18C6]. The NH4+ ion was fully included in a cavity, and was tightly bounded through strong hydrogen bonds to the oxygen atoms of 18C6.

Original languageEnglish
Pages (from-to)1861-1862
Number of pages2
JournalSynthetic Metals
Volume86
Issue number1 -3 pt 3
DOIs
Publication statusPublished - 1997 Jan 1
Externally publishedYes
EventProceedings of the 1996 International Conference on Science and Technology of Synthetic Metals, ICSM'96. Part 3 (of 3) - Snowbird, UT, USA
Duration: 1996 Jul 281996 Aug 2

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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