Crystal structure and electrical conductivity of [NH4+][18-crown-6][Ni(dmit)2]3

T. Akutagawa, T. Nakmaura, T. Inabe, A. E. Underhill

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

The [NH4+][Ni(dmit)2]3 complex, containing a macrocyclic molecule of 18-crown-6-ether (18C6), was obtained as [NH4+][18C6][Ni(dmit)2]3. This salt showed semiconducting behaviour with room temperature conductivity of 0.4 Scm-1. The crystal is composed of segregated non-uniform stack of Ni(dmit)2 and isolated ion-captured cavity of [NH4+][18C6]. The NH4+ ion was fully included in a cavity, and was tightly bounded through strong hydrogen bonds to the oxygen atoms of 18C6.

Original languageEnglish
Pages (from-to)1861-1862
Number of pages2
JournalSynthetic Metals
Volume86
Issue number1-3
DOIs
Publication statusPublished - 1997 Feb 28
Externally publishedYes

Keywords

  • Conductivity
  • Electrocrystallisation
  • Hall effect
  • Megnetotransport
  • Organic conductors based on radical cation and/or anion salts
  • Transport measurements

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Crystal structure and electrical conductivity of [NH<sub>4</sub><sup>+</sup>][18-crown-6][Ni(dmit)<sub>2</sub>]<sub>3</sub>'. Together they form a unique fingerprint.

Cite this