Abstract
The [NH4+][Ni(dmit)2]3 complex, containing a macrocyclic molecule of 18-crown-6-ether (18C6), was obtained as [NH4+][18C6][Ni(dmit)2]3. This salt showed semiconducting behaviour with room temperature conductivity of 0.4 Scm-1. The crystal is composed of segregated non-uniform stack of Ni(dmit)2 and isolated ion-captured cavity of [NH4+][18C6]. The NH4+ ion was fully included in a cavity, and was tightly bounded through strong hydrogen bonds to the oxygen atoms of 18C6.
Original language | English |
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Pages (from-to) | 1861-1862 |
Number of pages | 2 |
Journal | Synthetic Metals |
Volume | 86 |
Issue number | 1-3 |
DOIs | |
Publication status | Published - 1997 Feb 28 |
Externally published | Yes |
Keywords
- Conductivity
- Electrocrystallisation
- Hall effect
- Megnetotransport
- Organic conductors based on radical cation and/or anion salts
- Transport measurements
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering
- Metals and Alloys
- Materials Chemistry