Crystal engineering of tolane bridged nitronyl nitroxide biradicals: Candidates for quantum magnets

Prince Ravat, Yulia Borozdina, Yoshikazu Ito, Volker Enkelmann, Martin Baumgarten

    Research output: Contribution to journalArticlepeer-review

    11 Citations (Scopus)

    Abstract

    The tolane bridged nitronyl nitroxide biradicals with hydrogen bond donor and acceptor functional groups were synthesized. The magnetic measurements and the DFT calculations were performed to ascertain the influence of the functional groups on inter- and intramolecular magnetic exchange interactions. While upon functionalizing the tolane bridge the intramolecular exchange interactions remained nearly unchanged, the fine-tuning of intermolecular exchange interactions could be achieved by employing the crystal engineering approach. (Graph Presented).

    Original languageEnglish
    Pages (from-to)5840-5846
    Number of pages7
    JournalCrystal Growth and Design
    Volume14
    Issue number11
    DOIs
    Publication statusPublished - 2014 Nov 5

    ASJC Scopus subject areas

    • Chemistry(all)
    • Materials Science(all)
    • Condensed Matter Physics

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