Crystal and magnetic structures of Y2CrS4

Keitaro Tezuka, Yue Jin Shan, Hideo Imoto, Kenji Ohoyama

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Chromium(II) sulfide, Y2CrS4, prepared by a solid-state reaction of Y2S3 and CrS, showed an antiferromagnetic transition at 65 K. The neutron diffraction patterns at 10 and 90 K were both well refined with the space group Pca21. At 90 K, cell parameters were a=12.5518(13) Å, b=7.5245(8) Å, and c=12.4918(13) Å. At 10 K, magnetic peaks were observed, which could be indexed on the same unit cell. Magnetic moments of chromium ions were parallel to the b-axis and antiferromagnetically ordered in each set of the 4a sites.

Original languageEnglish
Pages (from-to)2133-2137
Number of pages5
JournalJournal of Physics and Chemistry of Solids
Volume68
Issue number11
DOIs
Publication statusPublished - 2007 Nov 1

Keywords

  • A. Chalcogenides
  • C. Neutron scattering
  • D. Crystal structure
  • D. Magnetic properties
  • D. Magnetic structure

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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