Crystal and electronic structures of quasi-one-dimensional halogen-bridged binuclear platinum complexes, {(CnH2n+1) 2NH2}4[Pt2(pop)4I] (n = 2-6)

Kouichi Takizawa; Tomohiko Ishii; Hitoshi Miyasaka; Hiroyuki Matsuzaka; Masahiro Yamashita; Takuya Kawashima; Hiroyuki Matsuzaki; Hideo Kishida; Hiroshi Okamoto

doi:10.1080/10587250210759

Crystal and electronic structures of quasi-one-dimensional halogen-bridged binuclear platinum complexes, {(C_nH_2n+1) ₂NH₂}₄[Pt₂(pop)₄I] (n = 2-6)

Kouichi Takizawa, Tomohiko Ishii, Hitoshi Miyasaka, Hiroyuki Matsuzaka, Masahiro Yamashita, Takuya Kawashima, Hiroyuki Matsuzaki, Hideo Kishida, Hiroshi Okamoto

Research output: Contribution to journal › Conference article › peer-review

5 Citations (Scopus)

Abstract

The crystal structures of {(C_nH_2n+1) ₂NH₂}₄[Pt₂(pop)₄I] (pop=O(PO₂H)₂^2-, n=2-6) have been determined. Judging from the results of the X-ray structural analyses and Raman spectra, 1-D electronic structures of these compounds are consider to be ...Pt ²⁺-Pt³⁺-X ...Pt²⁺-Pt³⁺-X... charge-polarized states.

Original language	English
Pages (from-to)	159-164
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	376
DOIs	https://doi.org/10.1080/10587250210759
Publication status	Published - 2002
Externally published	Yes
Event	Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States Duration: 2000 Dec 15 → 2000 Dec 18

Keywords

Halogen-bridged mixed-valence complexes
MMX-chain compounds

ASJC Scopus subject areas

Condensed Matter Physics

Access to Document

10.1080/10587250210759

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Takizawa, K., Ishii, T., Miyasaka, H., Matsuzaka, H., Yamashita, M., Kawashima, T., Matsuzaki, H., Kishida, H., & Okamoto, H. (2002). Crystal and electronic structures of quasi-one-dimensional halogen-bridged binuclear platinum complexes, {(C_nH_2n+1) ₂NH₂}₄[Pt₂(pop)₄I] (n = 2-6). Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 376, 159-164. https://doi.org/10.1080/10587250210759

Crystal and electronic structures of quasi-one-dimensional halogen-bridged binuclear platinum complexes, {(C_nH_2n+1) ₂NH₂}₄[Pt₂(pop)₄I] (n = 2-6). / Takizawa, Kouichi; Ishii, Tomohiko; Miyasaka, Hitoshi; Matsuzaka, Hiroyuki; Yamashita, Masahiro; Kawashima, Takuya; Matsuzaki, Hiroyuki; Kishida, Hideo; Okamoto, Hiroshi.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 376, 2002, p. 159-164.

Research output: Contribution to journal › Conference article › peer-review

Takizawa, K, Ishii, T, Miyasaka, H, Matsuzaka, H, Yamashita, M, Kawashima, T, Matsuzaki, H, Kishida, H & Okamoto, H 2002, 'Crystal and electronic structures of quasi-one-dimensional halogen-bridged binuclear platinum complexes, {(C_nH_2n+1) ₂NH₂}₄[Pt₂(pop)₄I] (n = 2-6)', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 376, pp. 159-164. https://doi.org/10.1080/10587250210759

Takizawa K, Ishii T, Miyasaka H, Matsuzaka H, Yamashita M, Kawashima T et al. Crystal and electronic structures of quasi-one-dimensional halogen-bridged binuclear platinum complexes, {(C_nH_2n+1) ₂NH₂}₄[Pt₂(pop)₄I] (n = 2-6). Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 2002;376:159-164. https://doi.org/10.1080/10587250210759

Takizawa, Kouichi ; Ishii, Tomohiko ; Miyasaka, Hitoshi ; Matsuzaka, Hiroyuki ; Yamashita, Masahiro ; Kawashima, Takuya ; Matsuzaki, Hiroyuki ; Kishida, Hideo ; Okamoto, Hiroshi. / Crystal and electronic structures of quasi-one-dimensional halogen-bridged binuclear platinum complexes, {(C_nH_2n+1) ₂NH₂}₄[Pt₂(pop)₄I] (n = 2-6). In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 2002 ; Vol. 376. pp. 159-164.

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abstract = "The crystal structures of {(CnH2n+1) 2NH2}4[Pt2(pop)4I] (pop=O(PO2H)22-, n=2-6) have been determined. Judging from the results of the X-ray structural analyses and Raman spectra, 1-D electronic structures of these compounds are consider to be ...Pt 2+-Pt3+-X ...Pt2+-Pt3+-X... charge-polarized states.",

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author = "Kouichi Takizawa and Tomohiko Ishii and Hitoshi Miyasaka and Hiroyuki Matsuzaka and Masahiro Yamashita and Takuya Kawashima and Hiroyuki Matsuzaki and Hideo Kishida and Hiroshi Okamoto",

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AU - Takizawa, Kouichi

AU - Ishii, Tomohiko

AU - Miyasaka, Hitoshi

AU - Matsuzaka, Hiroyuki

AU - Yamashita, Masahiro

AU - Kawashima, Takuya

AU - Matsuzaki, Hiroyuki

AU - Kishida, Hideo

AU - Okamoto, Hiroshi

PY - 2002

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AB - The crystal structures of {(CnH2n+1) 2NH2}4[Pt2(pop)4I] (pop=O(PO2H)22-, n=2-6) have been determined. Judging from the results of the X-ray structural analyses and Raman spectra, 1-D electronic structures of these compounds are consider to be ...Pt 2+-Pt3+-X ...Pt2+-Pt3+-X... charge-polarized states.

KW - Halogen-bridged mixed-valence complexes

KW - MMX-chain compounds

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