Crystal and electronic structures of quasi-one-dimensional halogen-bridged binuclear platinum complexes, {(CnH2n+1) 2NH2}4[Pt2(pop)4I] (n = 2-6)

Kouichi Takizawa, Tomohiko Ishii, Hitoshi Miyasaka, Hiroyuki Matsuzaka, Masahiro Yamashita, Takuya Kawashima, Hiroyuki Matsuzaki, Hideo Kishida, Hiroshi Okamoto

Research output: Contribution to journalConference articlepeer-review

5 Citations (Scopus)

Abstract

The crystal structures of {(CnH2n+1) 2NH2}4[Pt2(pop)4I] (pop=O(PO2H)22-, n=2-6) have been determined. Judging from the results of the X-ray structural analyses and Raman spectra, 1-D electronic structures of these compounds are consider to be ...Pt 2+-Pt3+-X ...Pt2+-Pt3+-X... charge-polarized states.

Original languageEnglish
Pages (from-to)159-164
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume376
DOIs
Publication statusPublished - 2002
Externally publishedYes
EventProceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States
Duration: 2000 Dec 152000 Dec 18

Keywords

  • Halogen-bridged mixed-valence complexes
  • MMX-chain compounds

ASJC Scopus subject areas

  • Condensed Matter Physics

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