Critical control by temperature and pressure of enantiodifferentiating anti-markovnikov photoaddition of methanol to diphenylpropene in near critical and supercritical carbon dioxide

Yasuhiro Nishiyama, Takehiko Wada, Tadashi Mori, Yoshihisa Inoue

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The enantiomeric excess of photoadduct obtained in the title reaction was critically manipulated not only by pressure (P) but also by temperature (T), exhibiting substantially different P-dependence profiles at different T, yet sharing a sudden leap near the critical density at each T, for which the difference in clustering property of methanol in near and supercritical CO 2 is thought to be responsible.

Original languageEnglish
Pages (from-to)1488-1489
Number of pages2
JournalChemistry Letters
Volume36
Issue number12
DOIs
Publication statusPublished - 2007 Dec 5
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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