[Cp2Fe2(CO)3(μ‐SitBu · NMI)]I: The First Silanetriyldiiron Complex

Yasuro Kawano; Hiromi Tobita; Hiroshi Ogino

doi:10.1002/anie.199108431

[Cp₂Fe₂(CO)₃(μ‐SitBu · NMI)]I: The First Silanetriyldiiron Complex

Yasuro Kawano, Hiromi Tobita, Hiroshi Ogino

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Another structure of the still new class of low‐valent silicon compounds bound to metals is represented by 1. The donor‐stabilized μ‐silanetriyldiiron complex cation (1)^⊕ is formed upon exchange of iodide for N‐methylimidazole (L) on complex 2. The FeSi distance is shorter than in complexes of type 2 and clearly indicates a multiple‐bond character. (Figure Presented.)

Original language	English
Pages (from-to)	843-844
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	30
Issue number	7
DOIs	https://doi.org/10.1002/anie.199108431
Publication status	Published - 1991 Jul

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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title = "[Cp2Fe2(CO)3(μ‐SitBu · NMI)]I: The First Silanetriyldiiron Complex",

abstract = "Another structure of the still new class of low‐valent silicon compounds bound to metals is represented by 1. The donor‐stabilized μ‐silanetriyldiiron complex cation (1)⊕ is formed upon exchange of iodide for N‐methylimidazole (L) on complex 2. The FeSi distance is shorter than in complexes of type 2 and clearly indicates a multiple‐bond character. (Figure Presented.)",

author = "Yasuro Kawano and Hiromi Tobita and Hiroshi Ogino",

year = "1991",

month = jul,

doi = "10.1002/anie.199108431",

language = "English",

volume = "30",

pages = "843--844",

journal = "Angewandte Chemie - International Edition",

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T1 - [Cp2Fe2(CO)3(μ‐SitBu · NMI)]I

T2 - The First Silanetriyldiiron Complex

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AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 1991/7

Y1 - 1991/7

N2 - Another structure of the still new class of low‐valent silicon compounds bound to metals is represented by 1. The donor‐stabilized μ‐silanetriyldiiron complex cation (1)⊕ is formed upon exchange of iodide for N‐methylimidazole (L) on complex 2. The FeSi distance is shorter than in complexes of type 2 and clearly indicates a multiple‐bond character. (Figure Presented.)

AB - Another structure of the still new class of low‐valent silicon compounds bound to metals is represented by 1. The donor‐stabilized μ‐silanetriyldiiron complex cation (1)⊕ is formed upon exchange of iodide for N‐methylimidazole (L) on complex 2. The FeSi distance is shorter than in complexes of type 2 and clearly indicates a multiple‐bond character. (Figure Presented.)

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