Covalently chemical modification of lithium ion-encapsulated fullerene: Synthesis and characterization of [Li +@PCBM]PF 6 -

Yutaka Matsuo; Hiroshi Okada; Masashi Maruyama; Hiroyasu Sato; Hiromi Tobita; Yoshihiro Ono; Kenji Omote; Kazuhiko Kawachi; Yasuhiko Kasama

doi:10.1021/ol301671n

Covalently chemical modification of lithium ion-encapsulated fullerene: Synthesis and characterization of [Li ⁺@PCBM]PF ₆ ^-

Yutaka Matsuo, Hiroshi Okada, Masashi Maruyama, Hiroyasu Sato, Hiromi Tobita, Yoshihiro Ono, Kenji Omote, Kazuhiko Kawachi, Yasuhiko Kasama

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

Covalently organic derivatization of [Li ⁺@C ₆₀]PF ₆ ^- to obtain Li ⁺-encapsulated PCBM, [Li ⁺@PCBM]PF ₆ ^-, is described. Synthetic procedures, electrochemical properties, light absorption properties, details of isomerization from [5,6]- to [6,6]-isomer, and X-ray crystal structure of [Li ⁺@PCBM]PF ₆ ^- are discussed.

Original language	English
Pages (from-to)	3784-3787
Number of pages	4
Journal	Organic letters
Volume	14
Issue number	14
DOIs	https://doi.org/10.1021/ol301671n
Publication status	Published - 2012 Jul 20

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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Covalently chemical modification of lithium ion-encapsulated fullerene : Synthesis and characterization of [Li ⁺@PCBM]PF ₆ ^-. / Matsuo, Yutaka; Okada, Hiroshi; Maruyama, Masashi; Sato, Hiroyasu; Tobita, Hiromi; Ono, Yoshihiro; Omote, Kenji; Kawachi, Kazuhiko; Kasama, Yasuhiko.

In: Organic letters, Vol. 14, No. 14, 20.07.2012, p. 3784-3787.

Research output: Contribution to journal › Article › peer-review

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title = "Covalently chemical modification of lithium ion-encapsulated fullerene: Synthesis and characterization of [Li +@PCBM]PF 6 -",

abstract = "Covalently organic derivatization of [Li +@C 60]PF 6 - to obtain Li +-encapsulated PCBM, [Li +@PCBM]PF 6 -, is described. Synthetic procedures, electrochemical properties, light absorption properties, details of isomerization from [5,6]- to [6,6]-isomer, and X-ray crystal structure of [Li +@PCBM]PF 6 - are discussed.",

author = "Yutaka Matsuo and Hiroshi Okada and Masashi Maruyama and Hiroyasu Sato and Hiromi Tobita and Yoshihiro Ono and Kenji Omote and Kazuhiko Kawachi and Yasuhiko Kasama",

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doi = "10.1021/ol301671n",

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T1 - Covalently chemical modification of lithium ion-encapsulated fullerene

T2 - Synthesis and characterization of [Li +@PCBM]PF 6 -

AU - Matsuo, Yutaka

AU - Okada, Hiroshi

AU - Maruyama, Masashi

AU - Sato, Hiroyasu

AU - Tobita, Hiromi

AU - Ono, Yoshihiro

AU - Omote, Kenji

AU - Kawachi, Kazuhiko

AU - Kasama, Yasuhiko

PY - 2012/7/20

Y1 - 2012/7/20

N2 - Covalently organic derivatization of [Li +@C 60]PF 6 - to obtain Li +-encapsulated PCBM, [Li +@PCBM]PF 6 -, is described. Synthetic procedures, electrochemical properties, light absorption properties, details of isomerization from [5,6]- to [6,6]-isomer, and X-ray crystal structure of [Li +@PCBM]PF 6 - are discussed.

AB - Covalently organic derivatization of [Li +@C 60]PF 6 - to obtain Li +-encapsulated PCBM, [Li +@PCBM]PF 6 -, is described. Synthetic procedures, electrochemical properties, light absorption properties, details of isomerization from [5,6]- to [6,6]-isomer, and X-ray crystal structure of [Li +@PCBM]PF 6 - are discussed.

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Covalently chemical modification of lithium ion-encapsulated fullerene: Synthesis and characterization of [Li ⁺@PCBM]PF ₆ ^-

Abstract

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