Covalently organic derivatization of [Li +@C 60]PF 6 - to obtain Li +-encapsulated PCBM, [Li +@PCBM]PF 6 -, is described. Synthetic procedures, electrochemical properties, light absorption properties, details of isomerization from [5,6]- to [6,6]-isomer, and X-ray crystal structure of [Li +@PCBM]PF 6 - are discussed.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry