Covalently chemical modification of lithium ion-encapsulated fullerene: Synthesis and characterization of [Li +@PCBM]PF 6 -

Yutaka Matsuo, Hiroshi Okada, Masashi Maruyama, Hiroyasu Sato, Hiromi Tobita, Yoshihiro Ono, Kenji Omote, Kazuhiko Kawachi, Yasuhiko Kasama

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44 Citations (Scopus)

Abstract

Covalently organic derivatization of [Li +@C 60]PF 6 - to obtain Li +-encapsulated PCBM, [Li +@PCBM]PF 6 -, is described. Synthetic procedures, electrochemical properties, light absorption properties, details of isomerization from [5,6]- to [6,6]-isomer, and X-ray crystal structure of [Li +@PCBM]PF 6 - are discussed.

Original languageEnglish
Pages (from-to)3784-3787
Number of pages4
JournalOrganic letters
Volume14
Issue number14
DOIs
Publication statusPublished - 2012 Jul 20

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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