Co2+(15-crown-5) magnetic supramolecular cation in [Ni(dmit)2]- πspin system

Tomoyuki Akutagawa, Sadafumi Nishihara, Nobuhiro Takamatsu, Tatsuo Hasegawa, Takayoshi Nakamura, Tamotsu Inabe

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

Magnetic cation of Co2+ was incorporated in a monovalent [Ni(dmit)2] (2-thioxo-l ,3-dithiole-4,5-dithiolate) salt by using the supramolecular framework of 15-crown-5. The π-spins of [Ni(dmit)2]~ formed a one-dimensional Heisenberg antiferromagnetic linear chain, while the d-spin of Co2+ behaved as a free S = 3/2 spin within the crystal.

Original languageEnglish
Pages (from-to)5871-5873
Number of pages3
JournalJournal of Physical Chemistry B
Volume104
Issue number25
DOIs
Publication statusPublished - 2000 Jun 29
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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