Correlation between site preference, superconductivity and magnetism in Pb2Sr2Y1 - xCax(Cu1 - yMy)3O8 (M = Fe, Co, Ni, Zn, Ga)

Yoji Koike; Masahiro Kaiwa; Tsuyoshi Kajitani; Masatsune Kato; Hiromu Sunagawa; Takashi Noji; Norio Kobayashi; Yukio Morii; Satoru Funahashi; Yoshitami Saito

doi:10.1016/0921-4534(93)90148-J

Correlation between site preference, superconductivity and magnetism in Pb₂Sr₂Y_{1 - x}Ca_x(Cu_{1 - y}M_y)₃O₈ (M = Fe, Co, Ni, Zn, Ga)

Yoji Koike, Masahiro Kaiwa, Tsuyoshi Kajitani, Masatsune Kato, Hiromu Sunagawa, Takashi Noji, Norio Kobayashi, Yukio Morii, Satoru Funahashi, Yoshitami Saito

ENG - Applied Physics

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Site preference of the partially substituted 3d metal M and superconducting and magnetic properties have been investigated for Pb₂Sr₂Y_{1 - x}Ca_x(Cu_{1 - y}M_y)₃O₈ (M = Fe, Co, Ni, Zn, Ga). It has been found from powder neutron diffraction that Fe atoms preferentially occupy the Cu(1) site in the oxygen-free Cu layer, while Co, Ni, Zn and Ga atoms occupy the Cu(2) site in the CuO₂ layer. From correlation between this site preference of M and the superconducting and magnetic properties, it has been concluded that the partial Cu(1)-site substitution shows little effect on the superconductivity and that there remains antiferromagnetic correlation between Cu²⁺ spins in the Cu(2) site in the normal state even for the high-T_c samples of x = 0.5 with T_c ≈ 80 K.

Original language	English
Pages (from-to)	409-420
Number of pages	12
Journal	Physica C: Superconductivity and its applications
Volume	211
Issue number	3-4
DOIs	https://doi.org/10.1016/0921-4534(93)90148-J
Publication status	Published - 1993 Jun 20

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Energy Engineering and Power Technology
Electrical and Electronic Engineering

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10.1016/0921-4534(93)90148-J

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Koike, Y., Kaiwa, M., Kajitani, T., Kato, M., Sunagawa, H., Noji, T., Kobayashi, N., Morii, Y., Funahashi, S., & Saito, Y. (1993). Correlation between site preference, superconductivity and magnetism in Pb₂Sr₂Y_{1 - x}Ca_x(Cu_{1 - y}M_y)₃O₈ (M = Fe, Co, Ni, Zn, Ga). Physica C: Superconductivity and its applications, 211(3-4), 409-420. https://doi.org/10.1016/0921-4534(93)90148-J

Correlation between site preference, superconductivity and magnetism in Pb₂Sr₂Y_{1 - x}Ca_x(Cu_{1 - y}M_y)₃O₈ (M = Fe, Co, Ni, Zn, Ga). / Koike, Yoji; Kaiwa, Masahiro; Kajitani, Tsuyoshi; Kato, Masatsune; Sunagawa, Hiromu; Noji, Takashi; Kobayashi, Norio; Morii, Yukio; Funahashi, Satoru; Saito, Yoshitami.

In: Physica C: Superconductivity and its applications, Vol. 211, No. 3-4, 20.06.1993, p. 409-420.

Research output: Contribution to journal › Article › peer-review

Koike, Y, Kaiwa, M, Kajitani, T, Kato, M, Sunagawa, H, Noji, T, Kobayashi, N, Morii, Y, Funahashi, S & Saito, Y 1993, 'Correlation between site preference, superconductivity and magnetism in Pb₂Sr₂Y_{1 - x}Ca_x(Cu_{1 - y}M_y)₃O₈ (M = Fe, Co, Ni, Zn, Ga)', Physica C: Superconductivity and its applications, vol. 211, no. 3-4, pp. 409-420. https://doi.org/10.1016/0921-4534(93)90148-J

Koike, Yoji ; Kaiwa, Masahiro ; Kajitani, Tsuyoshi ; Kato, Masatsune ; Sunagawa, Hiromu ; Noji, Takashi ; Kobayashi, Norio ; Morii, Yukio ; Funahashi, Satoru ; Saito, Yoshitami. / Correlation between site preference, superconductivity and magnetism in Pb₂Sr₂Y_{1 - x}Ca_x(Cu_{1 - y}M_y)₃O₈ (M = Fe, Co, Ni, Zn, Ga). In: Physica C: Superconductivity and its applications. 1993 ; Vol. 211, No. 3-4. pp. 409-420.

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abstract = "Site preference of the partially substituted 3d metal M and superconducting and magnetic properties have been investigated for Pb2Sr2Y1 - xCax(Cu1 - yMy)3O8 (M = Fe, Co, Ni, Zn, Ga). It has been found from powder neutron diffraction that Fe atoms preferentially occupy the Cu(1) site in the oxygen-free Cu layer, while Co, Ni, Zn and Ga atoms occupy the Cu(2) site in the CuO2 layer. From correlation between this site preference of M and the superconducting and magnetic properties, it has been concluded that the partial Cu(1)-site substitution shows little effect on the superconductivity and that there remains antiferromagnetic correlation between Cu2+ spins in the Cu(2) site in the normal state even for the high-Tc samples of x = 0.5 with Tc ≈ 80 K.",

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AU - Kobayashi, Norio

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AU - Funahashi, Satoru

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AB - Site preference of the partially substituted 3d metal M and superconducting and magnetic properties have been investigated for Pb2Sr2Y1 - xCax(Cu1 - yMy)3O8 (M = Fe, Co, Ni, Zn, Ga). It has been found from powder neutron diffraction that Fe atoms preferentially occupy the Cu(1) site in the oxygen-free Cu layer, while Co, Ni, Zn and Ga atoms occupy the Cu(2) site in the CuO2 layer. From correlation between this site preference of M and the superconducting and magnetic properties, it has been concluded that the partial Cu(1)-site substitution shows little effect on the superconductivity and that there remains antiferromagnetic correlation between Cu2+ spins in the Cu(2) site in the normal state even for the high-Tc samples of x = 0.5 with Tc ≈ 80 K.

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