Correlation between core-hole polarization and localized bond rupture probed by anisotropy in the photofragmentation of F 1s excited SF6

K. Ueda, Y. Shimizu, H. Chiba, M. Okunishi, K. Ohmori, J. B. West, Y. Sato, T. Hayaishi, H. Nakamatsu, T. Mukoyama

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Abstract

Anisotropic photofragmentation of SF6 following F 1s excitation is ascribed to the localization of the valence holes created as a result of the Auger decay of the F 1s core hole, itself polarized by excitation with linearly polarized light. Theoretical calculations based on the localized core-hole model are in reasonable agreement with the observation.

Original languageEnglish
Pages (from-to)3371-3374
Number of pages4
JournalPhysical Review Letters
Volume79
Issue number18
DOIs
Publication statusPublished - 1997 Jan 1

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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    Ueda, K., Shimizu, Y., Chiba, H., Okunishi, M., Ohmori, K., West, J. B., Sato, Y., Hayaishi, T., Nakamatsu, H., & Mukoyama, T. (1997). Correlation between core-hole polarization and localized bond rupture probed by anisotropy in the photofragmentation of F 1s excited SF6. Physical Review Letters, 79(18), 3371-3374. https://doi.org/10.1103/PhysRevLett.79.3371